Bulletin of the Chemical Society of Japan

Photo-induced alkoxybromination of olefins by N, N'-dibromo-2, 5-piperazinedione.

A Sera, H Yamada, K Itoh

Index: Sera, Akira; Yamada, Hiroshi; Itoh, Kuniaki Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 1 p. 219 - 221

Full Text: HTML

Citation Number: 8

Abstract

Irradiation of N, N′-dibronio-2, 5-piperazinedione in dichloromethane in the presence of an alcohol induced alkoxybromination of cyclohexene to give trans-1-bromo-2- alkoxycyclohexane in a good yield. The reaction was thought to proceed through an ionic mechanism.

Related Articles:

tert-Butylacetylene revisited. Improved synthesis. Methyl migration during bromination

[Collier,W.L.; Macomber,R.S. Journal of Organic Chemistry, 1973 , vol. 38, p. 1367 - 1369]

Reactions of a graded set of radicals with N-bromosuccinimide; two transition states

[Tlumak, Robert L.; Skell Philip S. Journal of the American Chemical Society, 1982 , vol. 104, # 25 p. 7267 - 7274]

The Reaction of t-Butylethylene and 1-Hexene with Bromine in Methanol1a

[Puterbaugh; Newman Journal of the American Chemical Society, 1957 , vol. 79, p. 3469]

The chemistry of 1, 8-naphthalenedicarboximidyl and phthalimidyl radicals

[Day, J. C.; Govindaraj, N.; McBain, D. S.; Skell, P. S.; Tanko, J. M. Journal of Organic Chemistry, 1986 , vol. 51, # 25 p. 4959 - 4963]

Complexes between N-bromosuccinimide and quaternary ammonium bromides and their role in the addition of bromine to olefins

[Finkelstein, Manuel; Hart, Shirley A.; Moore, W. Michael; Ross, Sidney D.; Eberson, Lennart Journal of Organic Chemistry, 1986 , vol. 51, # 18 p. 3548 - 3551]

More Articles...