Efficient One-Pot Procedures for the Preparation of Secondary Phosphines

…, NK Gusarova, AV Gusarov, HD Verkruijsse…

Index: Brandsma; Gusarova; Gusarov; Verkruijsse; Trofimov Synthetic Communications, 1994 , vol. 24, # 22 p. 3219 - 3223

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Citation Number: 11

Abstract

Abstract Secondary phosphines R2PH or RR'PH (R and R'= alkyl, cycloalkyl) have been obtained in good yields by preparing lithium phosphide from lithium, red phosphorus and t- butylalcohol in liquid ammonia and subsequent alkylation in the presence of alkali amide, prepared in the same flask.