Total synthesis of (+)-α-homonojirimycin

S Aoyagi, S Fujimaki, C Kibayashi

Index: Aoyagi, Sakae; Fujimaki, Satoshi; Kibayashi, Chihiro Journal of the Chemical Society, Chemical Communications, 1990 , # 20 p. 1457 - 1459

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Citation Number: 22

Abstract

The total synthesis of (+)-a-homonojirimycin, the first example of a naturally occurring azaheptose, was achieved in 13 steps utilizing the allylic alcohol 3 as a non-carbohydrate chiral building block. ... Published on 01 January 1990. Downloaded by google on 14/04/2016 21:18:34. ... View Article Online / Journal Homepage / Table of Contents for this issue ... 7 lv 5R=H 6R=Cbz iii r ... 11 10 Scheme 1 Reagents: i, (+)-DET, Ti(OPri)4, TBHP (ref. 5a); ii, ...