Tetrahedron

Direct force measurement between cucurbit [6] uril and spermine using atomic force microscopy

J Kim, Y Kim, K Baek, YH Ko, D Kim, K Kim

Index: Kim, Jeonghan; Kim, Youngkook; Baek, Kangkyun; Ko, Young Ho; Kim, Dongwoo; Kim, Kimoon Tetrahedron, 2008 , vol. 64, # 36 p. 8389 - 8393

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Citation Number: 13

Abstract

The rupture forces of individual host–guest complexes between surface-confined cucurbit [6] uril (CB [6]) and spermine derivatives were measured directly by atomic force microscopy (AFM). While 1, 2-dithiolane-attached spermine was immobilized on a gold-coated AFM tip, perallyloxyCB [6] was attached to an allyl-terminated self-assembled monolayer on a gold substrate by olefin metathesis reaction. A histogram and autocorrelation function analysis ...

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