The Synthesis of Hydroaromatic Compounds Containing Angular Groups. I. Hydrophenanthrene Series1

MS Newman, MD Farbman

Index: Newman; Farbman Journal of the American Chemical Society, 1944 , vol. 66, p. 1550

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Citation Number: 36

Abstract

Sept., 1944 SYNTHESES IN THEF HYDROPHENANTHRENE SERIES 1551 high. The dehydration of the hydroxy ester, 111, was accomplished in high yield by treating with thionyl chloride and pyridine. After hydrolysis a mixture of a solid and liquid unsaturated acid was obtained. The structure of the solid acid, IV, was established by ozonization, a 61y0 yield of the semicarbazide of I1 being isolated from the neutral products. On ozonization of ...

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