Organometallics

Reactivity of tetraisobutyldialuminum toward water, hydrogen chloride, toluene-3, 4-dithiol, pentacarbonylmanganese hydride, and diborane

MA Miller, EP Schram

Index: Miller, Mark A.; Schram, Eugene P. Organometallics, 1985 , vol. 4, p. 1362 - 1364

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Citation Number: 14

Abstract

The relative reactivities of Al-Al and Al-C bonds, Al2 (iB~) 4, have been examined employing the protonic reagents H30+, HCl (g), toluene-3, 4-dithiol, and HMII (CO)~ Excess H20, pH 1, results in 100% cleavage of both AI-A1 and A1-C bonds, whereas the A1-A1 bond exhibits