Chemistry Letters

Palladium-catalyzed synthesis of 2, 3-disubstituted allylamines by regioselective aminophenylation or aminoalkenylation of 1, 2-dienes.

I Shimizu, J Tsuji

Index: Shimizu, Isao; Tsuji, Jiro Chemistry Letters, 1984 , p. 233 - 236

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Citation Number: 68

Abstract

... ALLYLAMINES BY REGIOSELECTIVE AMINOPHENYLATION OR AMINOALKENYLATION OF 1,2-DIENES Isao SHIMIZU and Jiro TSUJI* Tokyo Institute of Technology, Meguro-ku, Tokyo 152 Reaction of 1,2-dienes, phenyl iodide or alkenyl bromides, and secondary amines in the presence of palladium-phosphine catalyst affords 2-phenyl or alkenyl allylic amines. ... e) GLC analysis. f) Single iso- mer, but the stereochemistry was not confirmed. Page 4. 236 ...