Journal of the American Chemical Society

BETA-PHENYLISOBUTYLMETHYL KETONE AND ITS DERIVATIVES. THE SYNTHESIS OF ALPHA-AND OF BETA-PHENYLISOVALERIANIC ACIDS

A Hoffman

Index: Hoffman Journal of the American Chemical Society, 1929 , vol. 51, p. 2545

Full Text: HTML

Citation Number: 22

Abstract

When mesityl oxide is added to benzene in the presence of anhydrous aluminum chloride, condensation takes place with the formation of a ketone C12H160. It is likely that the hydrogen chloride addition product of mesityl oxide is formed first and then reacts with the aluminum chloride setting free hydrogen chloride. Thus a trace of hydrogen chloride catalyzes the reaction and an evolution of the free gas takes place only at the very end.

Related Articles:

A New Catalytic Activity of Antimony (III) Chloride in Palladium (0)-Catalyzed Conjugate Addition of Aromatics to. alpha.,. beta.-Unsaturated Ketones and Aldehydes …

[Cho, Chan Sik; Motofusa, Shin-ichi; Ohe, Kouichi; Uemura, Sakae; Shim, Sang Chul Journal of Organic Chemistry, 1995 , vol. 60, # 4 p. 883 - 888]

Palladium-catalyzed conjugate addition of organosiloxanes to α, β-unsaturated carbonyl compounds and nitroalkenes

[Denmark, Scott E.; Amishiro, Nobuyoshi Journal of Organic Chemistry, 2003 , vol. 68, # 18 p. 6997 - 7003]

Palladium (II)-catalyzed hydroarylation of α, β-unsaturated aldehydes and ketones with triarylstibines in the presence of silver acetate

[Cho, Chan Sik; Tanabe, Koichiro; Uemura, Sakae Tetrahedron Letters, 1994 , vol. 35, # 8 p. 1275 - 1278]

Palladium (II)-Catalyzed Conjugate Addition of Aromatics to. ALPHA.,. BETA.-Unsaturated Ketones and Aldehydes with Arylantimony Compounds.

[Cho, Chan Sik; Motofusa, Shin-Ichi; Ohe, Kouichi; Uemura, Sakae Bulletin of the Chemical Society of Japan, 1996 , vol. 69, # 8 p. 2341 - 2348]

A New Convenient Synthesis of 4-Substituted 4-Methyl-2-pentanones

[Keuk,B.P. et al. Synthesis, 1977 , p. 638 - 640]

More Articles...