J. Phys. Org. Chem

Photochemistry of thiophene-S-oxide derivatives

MJ Heying, M Nag, WS Jenks

Index: Heying, Melanie J.; Nag, Mrinmoy; Jenks, William S. Journal of Physical Organic Chemistry, 2008 , vol. 21, # 11 p. 915 - 924

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Citation Number: 7

Abstract

The photochemical deoxygenation of dibenzothiophene-S-oxides (DBTOs) to dibenzothiophenes (DBTs) and the corresponding reactions of thiophene-S-oxide (TO) derivatives has a history going back into the 1970s, when first reported by Gurria and Posner.[1] Deoxygenation of other sulfoxides is known,[2–4] but it appears that the cases with the greatest chemical yield are generally limited to those in which the sulfur atom ...

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