Heterogeneous reactions: VII. Further studies on the heterogeneous gas/solid reactions of solid alkoxide bases with vaporized chloromethyldimethylhalosilanes

SP Hopper, MJ Tremelling, EW Goldman

Index: Hopper, Steven P.; Tremelling, Michael J.; Goldman, Emma W. Journal of Organometallic Chemistry, 1980 , vol. 190, # 3 p. 247 - 256

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Abstract

Abstract The results of the heterogeneous gas/solid reactions of chloromethyldimethylchloro (and fluoro) silane with solid lithium, sodium and potassium methoxide in the temperature range from 80–160 C are presented and discussed. Reaction with lithium methoxide serves as a clean, efficient high yield synthesis of chloromethyldimethylmethoxysilane without the complicating factors of side products or solvent to separate. The reactions of both the ...