Understanding the Unusual Regioselectivity in the Nucleophilic Ring-Opening Reactions of g em-Disubstituted Cyclic Sulfates. Experimental and Theoretical Studies

A Avenoza, JH Busto, F Corzana, JI García…

Index: Journal of Organic Chemistry, , vol. 68, # 11 p. 4506 - 4513

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Citation Number: 15

Abstract

... Journal of ... J. Org. Chem. , 2003, 68 (11), pp 4506–4513. DOI: 10.1021/jo034178q. Publication Date (Web): May 7, 2003. Copyright © 2003 American Chemical Society. ... Introduction. The important role of cyclic sulfates in organic synthesis has been described in two recent reviews. ...

A synthesis of optically active α-quaternary α-amino acids and esters by assembling three components, ketones,(R)-chloromethyl p-tolyl sulfoxide, and sodium azide, …

[Tetrahedron, , vol. 62, # 39 p. 9268 - 9279]

Understanding the Unusual Regioselectivity in the Nucleophilic Ring-Opening Reactions of g em-Disubstituted Cyclic Sulfates. Experimental and Theoretical Studies

Abstract

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