Formazans as β-diketiminate analogues. Structural characterization of boratatetrazines and their reduction to borataverdazyl radical anions

…, MJ Ferguson, R McDonald, BO Patrick…

Index: Gilroy, Joe B.; Ferguson, Michael J.; McDonald, Robert; Patrick, Brian O.; Hicks, Robin G. Chemical Communications, 2007 , # 2 p. 126 - 128

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Citation Number: 24

Abstract

It stands to reason that ligand skeletons similar in structure to 1 could also be useful in main group complex chemistry. For example, the transition metal 2 and main group 3 coordination chemistry of triazapentadienyl ligands 2 is beginning to develop. Formazans 3 are a class of molecules known for well over a century 4 which bear a strong structural resemblance to β-diketimines. However, the coordination chemistry of formazans has only received sporadic attention, 5 ...

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