Preparation of thermoresponsive polymers bearing amino acid diamide derivatives via RAFT polymerization

…, J Hu, J Sun, G He, Y Li, G Zhang

Index: Liu, Zhilei; Hu, Jiwen; Sun, Jianping; He, Guping; Li, Yinghui; Zhang, Ganwei Journal of Polymer Science, Part A: Polymer Chemistry, 2010 , vol. 48, # 16 p. 3573 - 3586

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Citation Number: 16

Abstract

Abstract We report here the synthesis of well-defined homopolymer bearing amino acid diamide, poly (N-acryloyl-L-valine N′-methylamide), via reversible addition fragmentation chain transfer (RAFT) polymerization using alkynyl-functionalized 2- dodecylsulfanylthiocarbonylsulfanyl-2-methyl-propionic acid propargyl alcohol ester as chain transfer agent (CTA) and 2, 2′-azobis (isobutyronitrile) as initiator. The effects of a ...

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