The transannular interaction germanium–nitrogen in germocanes: The influence of substituents

EK Lermontova, AA Selina, SS Karlov…

Index: Lermontova, Elmira Kh.; Selina, Anastasia A.; Karlov, Sergey S.; Churakov, Andrei V.; Howard, Judith A. K.; et al. Journal of Organometallic Chemistry, 2006 , vol. 691, p. 5710 - 5724

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Citation Number: 13

Abstract

The reaction of RN (CH2CH2OH) CHR1CR2R3OH (1–8) with a stoichiometric amount of tetrachloro (bromo) germane leads to the corresponding RN (CH2CH2O)(CHR1CR2R3O) GeHal2 (9–21). Difluorenylgermocane 22 was prepared by treatment of diethoxydifluorenylgermane with N-methyldiethanolamine. Different dialkanolamines were found to be successive precursors of dimethylgermocanes, RN (CH2CH2O)( ...