Synthesis and reactions of porphine-type metal complexes. 8. Carbon-carbon bond formation catalyzed by vitamin B12 and a vitamin B12 model compound. …

R Scheffold, M Dike, S Dike, T Herold…

Index: Scheffold, Rolf; Dike, Meera; Dike, Sunneel; Herold, Thomas; Walder, Lorenz Journal of the American Chemical Society, 1980 , vol. 102, # 10 p. 3642 - 3644

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Citation Number: 76

Abstract

An electron-exchange mechanism for the rearrangement can be written, and such a mechanism has been suggested for the ferrous ion catalyzed rearrangement of ascaridole (8) to compound 18." However, it seems unlikely that such a mechanism would give diepoxide 16 in even moderate yield, as rearrangements might be expected.

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