Molecules

Malonates in cyclocondensation reactions

W Stadlbauer, ES Badawey, G Hojas, P Roschger…

Index: Stadlbauer, Wolfgang; Badawey, El-Sayed; Hojas, Gerhard; Roschger, Peter; Kappe, Thomas Molecules, 2001 , vol. 6, # 4 p. 338 - 352

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Citation Number: 45

Abstract

Abstract: The use of malonates such as diethyl malonates 9,(chlorocarbonyl) ketenes 15 and bis (2, 4, 6-trichlorophenyl) malonates 18 as reagents for cyclocondensation with 1, 3- dinucleophiles to give six-membered heterocycles is described. Further attempts to use malonates such as bis (trimethylsilyl) malonates 19 and bis (carbamimidoyl) malonates 29 as new cyclocondensation agents are described.