[IrCl2Cp*(NHC)] Complexes as Highly Versatile Efficient Catalysts for the Cross??Coupling of Alcohols and Amines

A Prades, R Corberan, M Poyatos…

Index: Prades, Amparo; Corberan, Rosa; Poyatos, Macarena; Peris, Eduardo Chemistry - A European Journal, 2008 , vol. 14, # 36 p. 11474 - 11479

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Citation Number: 155

Abstract

Abstract A comparative study on the catalytic activity of a series of [IrCl 2 Cp*(NHC)] complexes in several C–O and C–N coupling processes implying hydrogen-borrowing mechanisms has been performed. The compound [IrCl 2 Cp*(I nBu)](Cp*= pentamethyl cyclopentadiene; I nBu= 1, 3-di-n-butylimidazolylidene) showed to be highly effective in the cross-coupling reactions of amines and alcohols, providing high yields in the production of ...

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