Photochemische Reaktionen. 16. Mitteilung. Photochemische Umwandlungen von O??Acetyl??1??dehydrotestosteron I

H Dutler, C Ganter, H Ryf, EC Utzinger…

Index: Dutler,H. et al. Helvetica Chimica Acta, 1962 , vol. 45, p. 2346 - 2381

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Citation Number: 26

Abstract

Abstract UV.-irradiation of O-acetyl-1-dehydro-testosterone in dioxane solution yields a mixture of photo-isomers from which four phenolic and five ketonic components have been isolated. Two of the phenols have been identified as the known 17-O-acetyl-1-methyl- estradiol and 1-hydroxy-17β-acetoxy-4-methyl-δ 1; 3; 5, 10-estratriene. The constitutions of the two remaining phenols and of four of the ketones have been elucidated.