Journal of Molecular Structure

Steric factors in the short-range solvation of secondary amines

JA Tayh, RM Scott

Index: Tayh, Jamal A.; Scott, Ronald M. Journal of Molecular Structure, 1990 , vol. 237, # 1 p. 297 - 305

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Citation Number: 5

Abstract

Abstract Steric aspects of the short-range solvation of proton transfer complexes between 2, 4-dinitrophenol and various secondary amines was studied in benzene—DMSO and benzene—dioxane mixed solvent systems. Diisopropylamine was hindered when compared with diethylamine, and 2, 2, 6, 6-tetramethylpiperidine was hindered when compared with 2, 6-dimethylpiperidine in forming the proton transfer complex. The smaller electron- ...