The generation and trapping of enantiopure bromonium ions

…, L Kwok, R Pouwer, JM Redmond, AJP White

Index: Braddock, D. Christopher; Hermitage, Stephen A.; Kwok, Lilian; Pouwer, Rebecca; Redmond, Joanna M.; White, Andrew J. P. Chemical Communications, 2009 , # 9 p. 1082 - 1084

Full Text: HTML

Citation Number: 11

Abstract

The bromonium ion is a species of fundamental interest in organic chemistry. 1 It was first proposed by Roberts and Kimball in 1937 to account for the well-established stereochemistry of the addition of molecular bromine to olefins. 2 Milestones in the history of the bromonium ion include Winstein and Lucas' experiment with 3-bromo-2-butanols to prove the existence of a cyclic symmetrical species, 3 the observation by Olah et al. of a bromonium ion by NMR 4 and the stable ...

Related Articles:

Bromochlorination of Alkenes with Dichlorobromate (1–) Ion. I

[Negoro; Ikeda Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 8 p. 2111 - 2115]

Tetraalkylphosphonium trihalides. Room temperature ionic liquids as halogenation reagents

[Cristiano, Rodrigo; Ma, Kefeng; Pottanat, George; Weiss, Richard G. Journal of Organic Chemistry, 2009 , vol. 74, # 23 p. 9027 - 9033]

The Addition of Bromine Chloride to Carbon—Carbon Double Bonds1

[Buckles; Long Journal of the American Chemical Society, 1951 , vol. 73, p. 998]

Bromochlorination of Alkenes with Dichlorobromate (1–) Ion. I

[Negoro; Ikeda Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 8 p. 2111 - 2115]

Bromochlorination of Alkenes with Dichlorobromate (1–) Ion. I

[Negoro; Ikeda Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 8 p. 2111 - 2115]

More Articles...