Journal of the American Chemical Society

The Addition of Bromine Chloride to Carbon—Carbon Double Bonds1

RE Buckles, JW Long

Index: Buckles; Long Journal of the American Chemical Society, 1951 , vol. 73, p. 998

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Citation Number: 23

Abstract

A mixture of N-bromoacetamide and hydrogen chloride has been used as a source of the elements of bromine chloride for addition to ethylene, styrene, cinnamic acid, cis-stilbene and trans-stilbene. The structures of the chlorobromides which were obtained support the polar mechanism of addition in which positive bromine is transferred to the double bond to form a complex, eg, the bromonium ion, which is attacked by chloride ion to give the ...

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