Syntheses with. alpha.-heterosubstituted phosphonate carbanions. 10. Autoxidation of the anion

H Zimmer, RE Koenigkramer, RL Cepulis…

Index: Zimmer, Hans; Koenigkramer, Rusty E.; Cepulis, R. L.; Nene, D. M. Journal of Organic Chemistry, 1980 , vol. 45, p. 2018 - 2020

Full Text: HTML

Citation Number: 12

Abstract

Scheme I11 oxidation of ketones in basic solutionsJO that the reaction is somewhat similar to the one in Scheme 111. Though preparatively not as valuable as the autoxidation of triphenylmethyleneph~ sphoranes~-~ and of certain phosphine oxides6 the method described here might very well be the method of choice to transform aromatic aldehydes in a two-step synthesis into the corresponding acid anilides, especially 4-nitroanilides (Table ...

Related Articles:

Amination of nitrobenzene via nucleophilic aromatic substitution for hydrogen: direct formation of aromatic amide bonds

[Stern, Michael K.; Cheng, Brian K. Journal of Organic Chemistry, 1993 , vol. 58, # 24 p. 6883 - 6888]

Amination of nitrobenzene via nucleophilic aromatic substitution for hydrogen: direct formation of aromatic amide bonds

[Stern, Michael K.; Cheng, Brian K. Journal of Organic Chemistry, 1993 , vol. 58, # 24 p. 6883 - 6888]

Rearrangement of imidoyl nitrates to N-nitro amides: an intramolecular [1, 3] O-to-N migration of a nitro group

[Carvalho, Emilia; Iley, Jim; Rosa, Eduarda Journal of the Chemical Society, Chemical Communications, 1988 , # 18 p. 1249 - 1250]

Complexes of silicon and phosphorus chlorides with nitrogen-containing bases as the condensing agents in the synthesis of amides

[Besgubenko, L. V.; Pipko, S. E.; Sinitsa, A. D. Russian Journal of General Chemistry, 2012 , vol. 82, # 8 p. 1382 - 1390,9 Zhurnal Obshchei Khimii, 2012 , vol. 82, # 8 p. 1302 - 1310,9]

Amination of nitrobenzene via nucleophilic aromatic substitution for hydrogen: direct formation of aromatic amide bonds

[Stern, Michael K.; Cheng, Brian K. Journal of Organic Chemistry, 1993 , vol. 58, # 24 p. 6883 - 6888]

More Articles...