N, N-Bis [ethoxy (methyl) silylmethyl] methylamines MeN [CH2SiMem (OEt) 3-m] 2 (m= 0-2). Synthesis and Reactions with Phenol
NF Lazareva, EI Brodskaya
Index: Lazareva; Brodskaya Russian Journal of General Chemistry, 2001 , vol. 71, # 2 p. 201 - 205
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Citation Number: 6
Abstract
Abstract Previously unknown N, N-bis [ethoxy (methyl) silylmethyl] amines MeN [CH 2 SiMe m (OEt) 3-m] 2 (m= 0-2) were synthesized. According to UV spectral data, only MeN [CH 2 SiMe 2 (OEt)] 2 form hydrogen bond with phenol in a heptane solution. The amines with m= 0 and 1 fail to forms hydrogen bond with phenol [under the same conditions, N- (triethoxysilylmethyl) dimethylamine Me 2 NCH 2 Si (OEt) 3 forms a strong hydrogen bond ...
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