Multinuclear 1D and 2D NMR Investigations on the Interaction between the Pyrimidic Nucleotides 5′??CMP, 5′??dCMP, and 5′??UMP and Diethyltin Dichloride in …

…, M Biesemans, M Gielen, A Garoufis…

Index: Ghys, Laurent; Biesemans, Monique; Gielen, Marcel; Garoufis, Achilleas; Hadjiliadis, Nick; Willem, Rudolph; Martins, Jose C. European Journal of Inorganic Chemistry, 2000 , # 3 p. 513 - 522

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Citation Number: 38

Abstract

Abstract The interactions between diethyltin dichloride and 5′-CMP, 5′-dCMP, and 5′- UMP in aqueous solution were investigated by multinuclear 1D and 2D NMR techniques including 119 Sn, 15 N and 31 P nuclei. These studies were combined with electrospray mass spectrometry, infrared spectroscopy, solid state 13 C, 31 P and 117 Sn CP-MAS NMR, and elemental analysis. As demonstrated by 31 P-1 H HOESY spectroscopy, the diethyltin ...