Tetrahedron Letters

McMurry coupling of aryl aldehydes and imino pinacol coupling mediated by Ti (Oi-Pr) 4/Me 3 SiCl/Mg reagent

S Okamoto, JQ He, C Ohno, Y Oh-iwa, Y Kawaguchi

Index: Okamoto, Sentaro; He, Jing-Qian; Ohno, Chihaya; Oh-iwa, Yuhji; Kawaguchi, Yuhki Tetrahedron Letters, 2010 , vol. 51, # 2 p. 387 - 390

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Citation Number: 22

Abstract

Ti(O-i-Pr) 4 /Me 3 SiCl/Mg reagent mediated McMurry coupling of aryl aldehydes to biaryl olefins at near room temperature. This low valent titanium (LVT) reagent also mediated the coupling of aldimines to 1,2-diamines (imino pinacol coupling). ... Ti(O-i-Pr) 4 /Me 3 SiCl/Mg reagent mediated McMurry coupling of aryl aldehydes to biaryl olefins at near room temperature and the reagent also coupled aldimines to 1,2-diamines (imino pinacol coupling). ... Low valent titanium ( ...

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