First total synthesis and absolute configuration of the styryl lactone gonioheptolide A

S Gupta, M Rajagopalan, MM Alhamadsheh…

Index: Gupta, Shuchi; Rajagopalan, Murali; Alhamadsheh, Mamoun M.; Tillekeratne, L. M. Viranga; Hudson, Richard A. Synthesis, 2007 , # 22 p. 3512 - 3518

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Citation Number: 8

Abstract

Abstract Efficient asymmetric syntheses of both naturally occurring and non-naturally occurring enantiomers of gonioheptolide A are reported. The absolute configuration of (+)- gonioheptolide A was established by NOESY, Mosher ester analysis, and comparison with the specific rotation of the isolated (+)-gonioheptolide A.

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