The Journal of Organic Chemistry

Carbamates. IV. The Reactions of Disubstituted Carbamates with Alcohols

NG GAYLORD

Index: Gaylord,N.G. Journal of Organic Chemistry, 1960 , vol. 25, p. 1874 - 1876

Full Text: HTML

Citation Number: 9

Abstract

The reaction of ethyl N, Ndisubstituted carbamates with alcohols in the presence of the sodium alkoxide of the alcohol yields either carbamates or carbonates, apparently 1t8 a function of the relative base strengths of the disubstituted amine and the alkoxide. Thus, the reactions of isobutyl alcohol with ethyl N, N-diethyl-and N-ethyl-N-phenylcarbamates, and benzyl alcohol with ethyl N-ethyl-N-phenylcarbamate and N-N'-dicarbethoxypiperazine ...

Related Articles:

A Novel Synthesis of Carboxylic Esters from 2-Methyl-4, 6-pyrimidyl Dicarbonates and Grignard Reagents

[Lee, Jae In Bulletin of the Korean Chemical Society, 2011 , vol. 32, # 5 p. 1765 - 1768]

A DIRECT SYNTHESIS OF CARBAMATE ESTER PROM CARBON DIOXIDE, AMINE AND ALKYL HALIDE

[Yoshida, Yasuhiko; Ishhi, Shigeru; Yamashita, Tadataka Chemistry Letters, 1984 , p. 1571 - 1572]

More Articles...