Cobaltocenium Fluoride: A Novel Source of" Naked" Fluoride Formed by Carbon-Fluorine Bond Activation in a Saturated Perfluorocarbon

…, RG Harrison, TG Richmond

Index: Bennett, Brian K.; Harrison, Roger G.; Richmond, Thomas G. Journal of the American Chemical Society, 1994 , vol. 116, # 24 p. 11165 - 11166

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Citation Number: 73

Abstract

There continues to be considerable interest in the generation of highly nucleophilic sources of fluoride, often termed" naked'fluoride, for applications in organic2 and inorganic~ ynthesis.~ Most approaches involve synthesis of elaborate counterions4 followed by ion exchange or reaction with HF and appropriate drying procedure^.^-^ Although saturated perfluorocarbons are normally chemically inert, recent studies in our lab8 as well as by ...