Tetrahedron letters

Indirect electrochemical methods of nitration: Novel nitroacetamidation of dienes

AJ Bloom, M Fleischmann, JM Mellor

Index: Bloom, A John; Fleischmann, Martin; Mellor, John M Tetrahedron Letters, 1984 , vol. 25, # 43 p. 4971 - 4974

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Citation Number: 18

Abstract

Abstract Solutions of nitronium tetrafluoroborate in acetonitrile prepared by anodic oxidation of nitrogen dioxide, efficiently nitrate aromatics, enolsilyethers, alkenes and conjugated dienes to afford respectively nitroaromatics, α-nitroketones, vicinal nitroamides and mixtures of nitroacetamides by 1, 2-and 1, 4-addition.