Short, Facile, and High??Yielding Synthesis of Extremely Efficient Pincer??Type Suzuki Catalysts Bearing Aminophosphine Substituents

JL Bolliger, O Blacque, CM Frech

Index: Bolliger, Jeanne L.; Blacque, Olivier; Frech, Christian M. Angewandte Chemie - International Edition, 2007 , vol. 46, # 34 p. 6514 - 6517

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Citation Number: 82

Abstract

The Suzuki reaction is one of the most efficient methods for forming CÀC bonds,[1, 2] and is nowadays an indispensable tool in organic synthesis for the formation of symmetric and nonsymmetric biaryl compounds by catalysis.[3] Many palladium complexes have been used to promote the Suzuki–Miyaura cross-coupling reaction and, whilst some are very efficient and allow the use of sterically hindered substrates and even aryl chlorides at very ...