Palladium??Catalyzed Asymmetric 1, 4??Addition of Diarylphosphines to Nitroalkenes for the Synthesis of Chiral P, N??Compounds

JJ Feng, M Huang, ZQ Lin…

Index: Feng, Jian-Jun; Huang, Miao; Lin, Zi-Qi; Duan, Wei-Liang Advanced Synthesis and Catalysis, 2012 , vol. 354, # 16 p. 3122 - 3126

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Citation Number: 24

Abstract

Abstract A highly stereoselective asymmetric 1, 4-addition of diarylphosphines to nitroalkenes catalyzed by a bis (phosphine) pincer-palladium complex has been developed for the synthesis of chiral P, N compounds with good to excellent enantioselectivities (up to 94% ee) under mild conditions.

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