Tetrahedron Letters

Synthetic studies toward kaitocephalin

TP Loh, YK Chok, Z Yin

Index: Loh, Teck-Peng; Chok, Yew-Keong; Yin, Zheng Tetrahedron Letters, 2001 , vol. 42, # 44 p. 7893 - 7897

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Citation Number: 11

Abstract

Synthetic studies toward the total synthesis of kaitocephalin 1, whose stereochemical assignment was undetermined at the time of commencement, were undertaken in an attempt to provide a general methodology to gain access to any one of all 32 possible stereoisomers. An interesting, unexpected, result was observed in the anticipated stereoselective key aldol reaction.

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