InCl3??Catalyzed Synthesis of 1, 2??Dimetallic Compounds by Direct Insertion of Aluminum or Zinc Powder

…, T Klatt, K Koszinowski, P Knochel

Index: Bluemke, Tobias D.; Klatt, Thomas; Koszinowski, Konrad; Knochel, Paul Angewandte Chemie - International Edition, 2012 , vol. 51, # 39 p. 9926 - 9930

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Citation Number: 14

Abstract

Organometallic species containing two carbon–metal bonds in the same molecule (dimetallic compounds) often show special reactivity patterns and offer unique synthetic applications.[1] The chemical properties of such organometallic species depend on the nature of the two metals and their topological proximity.[2] Whereas 1, n-dimetallic species (n= 1, 3–6)[3] have been prepared by several methods and efficiently employed as multi- ...