A Combined Neutralization??Reionization Mass Spectrometric and Theoretical Study of Oxyallyl and Other Elusive [C3, H4, O] Neutrals

…, W Zummack, JH Bowie, H Schwarz

Index: Schalley, Christoph A.; Blanksby, Stephen; Harvey, Jeremy N.; Schroeder, Detlef; Zummack, Waltraud; Bowie, John H.; Schwarz, Helmut European Journal of Organic Chemistry, 1998 , # 6 p. 987 - 1009

Full Text: HTML

Citation Number: 26

Abstract

Abstract Five different anionic [C 3, H 4, O]·− isomers, ie the radical anions of acrolein, acetyl carbene, formyl methyl carbene, methoxy vinylidene, and oxyallyl are generated in an ion beam mass spectrometer and subjected to neutralization-reionization (NR) mass spectrometric experiments including neutral and ion decomposition difference (NIDD) mass spectrometry; the latter allows for the examination of the neutrals′ unimolecular reactivity. ...

Related Articles:

Asymmetric reduction of aliphatic short-to long-chain. beta.-keto acids by use of fermenting bakers' yeast

[Utaka, Masanori; Watabu, Hisashi; Higashi, Hiroshi; Sakai, Takashi; Tsuboi, Sadao; Torii, Sigeru Journal of Organic Chemistry, 1990 , vol. 55, p. 3917 - 3921]

Reaction of the anionic acylmethylidyne cluster [Ru3 (CO) 9 (. mu. 3-CO)(. mu. 3-CC (O) CH3)]-with carbon monoxide and hydrogen: reversible carbon-carbon and …

[Sailor, Michael J.; Sabat, Michal; Shriver, Duward F. Organometallics, 1988 , vol. 7, p. 728 - 736]

Combined deuterium nuclear magnetic resonance and mass-spectrometric studies of the exchange reactions of ketones over supported metal catalysts

[Pope, Christopher; Kemball, Charles; McDougall, Gordon S. Journal of the Chemical Society, Faraday Transactions, 1990 , vol. 86, # 4 p. 747 - 752]

The effect of surface hydroxyl groups upon the deactivation of excited triplet acetone adsorbed on porous vycor glass

[ANPO, Masakazu Chemistry Letters, 1987 , p. 1221 - 1224]

More Articles...