The Journal of Organic Chemistry

Thionophosphine Sulfides. II. Preparation and Chlorination of Phosphonodithioic Acids1a

JP Chupp, PE Newallis

Index: Chupp,J.P.; Newallis,P.E. Journal of Organic Chemistry, 1962 , vol. 27, p. 3832 - 3835

Full Text: HTML

Citation Number: 21

Abstract

The reaction of thionophosphine sulfides (RPS,),, with alcohols and phenols has been found to give excellent yields of the corresponding 0-alkyl and 0-aryl phosphonodithioic acids. A number of halo-alkanols, alkenols, and dihydric alcohols, as well as simple primary and secondary alcohols have been smoothly converted to phosphonodithioic acids. Chlorination of these 0-alkyl and 0-aryl phosphonodithioic acids has been found to yield the ...