Iodomethaneboronic esters and aminomethaneboronic esters
DS Matteson, D Majumdar
Index: Matteson,D.S.; Majumdar,D. Journal of Organometallic Chemistry, 1979 , vol. 170, p. 259 - 264
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Citation Number: 41
Abstract
Abstract An efficient preparation of pinacol iodomethaneboronate and dibutyl iodomethaneboronate from the respective (phenylthio) methaneboronic esters has been devised, using the reaction with methyl iodide. Pinacol iodomethaneboronate reacts efficiently wit tertiary amines to form the crystalline quaternary ammonium salts. Dibutyl iodomethaneboronate reacts with excess piperidine or morpholine in ether to precipitate ...
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