Synthesis of Glycidyl??5??(carboxyethyl??1H??tetrazole) polymer and 1, 2??Bis (5??carboxyethyl??1H??tetrazolyl) ethane as Polymeric Precursor

FM Betzler, TM Klapötke…

Index: Betzler, Franziska M.; Klapoetke, Thomas M.; Sproll, Stefan M. European Journal of Organic Chemistry, 2013 , # 3 p. 509 - 514

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Citation Number: 3

Abstract

Abstract The synthesis of the nitrogen-rich glycidyl-5-(carboxyethyl-1H-tetrazole) polymer (4) by the reaction of glycidyl azide polymer (GAP) and ethyl cyanoformate (2) is described. Moreover, the polymer precursor 1, 2-bis (5-carboxyethyl-1H-tetrazolyl) ethane (3), containing two tetrazole moieties, was obtained by reacting compound 2 and 1, 2- diazidoethane (1). The substances were characterized by using vibrational spectroscopy ( ...