Tetrahedron Letters

Stereo-and regioselective routes to allylic silanes

E Negishi, FT Luo, CL Rand

Index: Negishi, Ei-ichi; Luo, Fen-Tair; Rand, Cynthia L. Tetrahedron Letters, 1982 , vol. 23, p. 27 - 30

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Citation Number: 80

Abstract

Abstract The Ni-or Pd-catalyzed reaction of alkenyl iodides with Me 3 SiCH 2 Mgcl provides various types of allytrimethylsilanes in excellent yields in a highly stereo-and regioselective manner, while the Zr-catalyzed carboalumination of Me 3 SiCH 2 C CH followed by replacement of Al with carbon groups by known reactions produces allylsilanes represented by 2.

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