Synthesis of Disubstituted Phosphinates via Palladium??Catalyzed Hydrophosphinylation of H??Phosphinic Acids

C Petit, F Fecourt, JL Montchamp

Index: Petit, Christelle; Fecourt, Fabien; Montchamp, Jean-Luc Advanced Synthesis and Catalysis, 2011 , vol. 353, # 11-12 p. 1883 - 1888

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Citation Number: 14

Abstract

Abstract The first metal-catalyzed hydrophosphinylation of unsaturated hydrocarbons with H- phosphinic acids is described. A strategy to activate the P [BOND] H bond through control of the tautomeric equilibrium using ethylene glycol is described. The reactions also avoid chromatographic purification.