Tetrahedron letters

Straightforward synthesis of α, β-epoxysilanes from terminal epoxides by lithium 2, 2, 6, 6-tetramethylpiperidide-mediated deprotonation-in situ silylation

DM Hodgson, NJ Reynolds, SJ Coote

Index: Hodgson, David M.; Reynolds, Nigel J.; Coote, Steven J. Tetrahedron Letters, 2002 , vol. 43, # 44 p. 7895 - 7897

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Citation Number: 22

Abstract

Download PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Lithiation-in situ silylation of simple terminal epoxides using lithium 2,2,6,6-tetramethylpiperidide in combination with trimethylsilyl chloride provides a direct and experimentally convenient process for the synthesis of trans-α,β-epoxysilanes. ... A study of the LTMP-mediated in situ ...

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Straightforward synthesis of α, β-epoxysilanes from terminal epoxides by lithium 2, 2, 6, 6-tetramethylpiperidide-mediated deprotonation-in situ silylation

Abstract

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