Australian journal of chemistry

Selectivity in radical reactions of alanylglycine anhydride derivatives

CLL Chai, DB Hay, AR King

Index: Chai, Christina L.L.; Hay, Darren B.; King, Alison R. Australian Journal of Chemistry, 1996 , vol. 49, # 5 p. 605 - 610

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Citation Number: 5

Abstract

Abstract Functionalization of N, N′-disubstituted alanylglycine anhydrides under radical conditions is described. The radical (7), generated (i) from reactions of N, N'-disubstituted alanylglycine anhydrides with N-bromosuccinimide, and (ii) from related bromo compounds by reaction with tributyltin deuteride, undergoes carbon-bromine and carbon-deuterium bond formation with moderate to high diastereoselectivities depending on the N- ...