Tetrahedron

Reaction of 2, 6-dimethyl-4-methoxybenzaldehyde with methylmagnesium iodide and some properties of the reaction products

T Kamikawa, M Nakatani, T Kubota

Index: Kamikawa,T. et al. Tetrahedron, 1968 , vol. 24, p. 2091 - 2100

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Citation Number: 6

Abstract

Treatment of 2, 6-dimethyl-4-methoxybenzaldehyde with MeMgI afforded two isomeric ethers,(1A and 1B), instead of the desired 1-(2, 6-dimethyl-4-methoxyphenyl) ethanol. The NMR spectra of the high-melting isomer (1B) showed the presence of hindered rotation of aromatic Me groups. The reactions and properties of these ethers and other related ethers were examined.

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[Pelter, Andrew; Drake, Robert Tetrahedron, 1994 , vol. 50, # 48 p. 13775 - 13800]

Hindered organoboron groups in organic chemistry. 27. Preparations and some properties of alkylbis (2, 6-dimethyl-4-methoxyphenyl) boranes ((DMP) 2 BR)

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