Photolysis of cyclopropyl ketones in the vapor phase and in solution

JN Pitts Jr, DG Marsh, K Schaffner…

Index: Marsh,D.G. et al. Journal of the American Chemical Society, 1971 , vol. 93, # 2 p. 333 - 338

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Citation Number: 8

Abstract

Abstract: The vapor-phase (at 120O) and solution photochemistry of dicyclopropyl ketone (I), methyl 2, 2-dimethylcyclopropyl ketone (11), cyclopropyl 2, 2-dimethylcyclopropyl ketone (111), propyl cyclopropyl ketone (IV), 3-butenyl cyclopropyl ketone (V; in the vapor phase), and 3-methyl-3-butenyl cyclopropyl ketone (VI; in solution) has be $ n investigated. Dicyclopropyl ketone (I), when irradiated in the vapor phase in its n+ T* band at 2537- ...