Synthesis of 5-isothiocyanato-1, 10-phenanthroline

NN Khimich, NP Obrezkov, LA Koptelova

Index: Khimich; Obrezkov; Koptelova Russian Journal of Organic Chemistry, 2006 , vol. 42, # 4 p. 555 - 557

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Citation Number: 2

Abstract

Abstract Reduction of 5-nitro-1, 10-phenanthroline with hydrogen over Pd/C, followed by the treatment of 1, 10-phenanthrolin-5-amine with thiophosgene in the presence of sodium acetate, gave 5-isothiocyanato-1, 10-phenanthroline which is a thermally stable highly reactive ligand capable of quantitatively forming covalently bonded nanohybrid structures in a system transition metal complex-silica under mild conditions.