Dynamics of endoergic substitution reactions. II. Br+ {C2H2Cl2}→ Cl+ {C2H2ClBr}

GN Robinson, RE Continetti, YT Lee

Index: Robinson, Gary N.; Continetti, Robert E.; Lee, Yuan T. Journal of Chemical Physics, 1988 , vol. 89, # 10 p. 6238 - 6246

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Citation Number: 6

Abstract

We have extended the crossed beams studies described in the preceding paper to the reactions of Br atoms with 1, 1??and trans??dichloroethylene. The shapes of the product translational energy distributions and excitation functions for both reactions support our previous conclusion that Cl elimination from Br–R–Cl collision complexes can compete with Br elimination only in the limit that few vibrational modes of the complex are active in ...