Polyhedron

Functionalized bipyridyl rhodium complex capable of electrode attachment for regeneration of NADH

D Sivanesan, S Yoon

Index: Sivanesan, Dharmalingam; Yoon, Sungho Polyhedron, 2013 , vol. 57, p. 52 - 56

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Citation Number: 4

Abstract

A Rh (III) complex having a functionalized bpy-OH ligand that is potentially linkable to electrode surfaces was synthesized and fully characterized. The hydrido complex, which could be generated either electrochemically by cathodic reduction of the [η5-Cp∗ Rh (bpy- OH) Cl] Cl complex at− 771mV (versus Ag/AgCl) or chemically with formate, transformed NAD+ efficiently into NADH with a TOF= 710 at 60° C.

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