Analytical Chemistry

P-fluorobenzoyl chloride for characterization of active hydrogen functional groups by fluorine-19 nuclear magnetic resonance spectrometry

MP Spratt, HC Dorn

Index: Spratt, M. P.; Dorn, H. C. Analytical Chemistry, 1984 , vol. 56, # 12 p. 2038 - 2043

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Citation Number: 19

Abstract

The base-catalyzed reactions of p 4luorobenzoyl chloride provkle a convenient method for 'OF NMR analysls of alcohols, phenols, carboxylic acids, amlnes, and thiols. The'OF chemlcal shlft and yleld data for p-fluorobenzoyl derlvatives for nearly 100 compounds are presented. The yield data for these p-fluorobenroyi derlvatlves suggest a slmple, and In many cases, quantltatlve method for Introducing a fluorine tagglng group. The 'OF ...