Synlett

Palladium-Catalyzed Monoarylation of Aryl Amine with Aryl Tosylates

X Xie, G Ni, F Ma, L Ding, S Xu, Z Zhang

Index: Xie, Xiaomin; Ni, Gang; Ma, Fangfang; Ding, Lina; Xu, Sheng; Zhang, Zhaoguo Synlett, 2011 , # 7 p. 955 - 958

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Citation Number: 10

Abstract

Abstract The bulky and electron-rich MOP-type ligand was efficient for the Pd-catalyzed amination of aryl tosylates. The in situ generated Pd (0) was a more efficient catalyst precursor than Pd (dba) 2. In the presence of Pd (OAc) 2, PhB (OH) 2, and a hindered and electron-rich MOP-type ligand, a variety of primary aryl amines reacted with various aryl tosylates to form the corresponding secondary aryl amines in high yields with high ...

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