Tetrahedron letters

Preparation and optical resolution of novel 5, 10-diaryloctaethylporphyrins with C 2 symmetry

Y Aoyama, K Saita, H Toi, H Ogoshi, Y Okamoto

Index: Aoyama, Yasuhiro; Saita, Kazumi; Toi, Hiroo; Ogoshi, Hisanobu; Okamoto, Yoshio Tetrahedron Letters, 1987 , vol. 28, # 41 p. 4853 - 4856

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Citation Number: 16

Abstract

Abstract Zinc complex of 5, 10-bis (2-hydroxynaphthyl) octaethylporphyrin was prepared by coupling tripyrrole and monopyrrole derivatives in the presence of 2- hydroxynaphthaldehyde. The chiral trans isomer and di (benzyl ether) derivative derived therefrom were successfully resolved into enantiomers by means of HPLC.