Inorganic Chemistry Communications

Bis-benzimidazolyl diamide copper (II) complexes: Synthesis, crystal structure and oxidation of substituted amino phenols

G Ahuja, P Mathur

Index: Ahuja, Gauri; Mathur, Pavan Inorganic Chemistry Communications, 2012 , vol. 17, p. 42 - 48

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Citation Number: 8

Abstract

A new tetradentate ligand N, N′-Bis (1-butyl-benzimidazol-2-yl-methyl)-hexane-1, 6- dicarboxamide (b-GBSA) has been utilized to synthesize mononuclear copper (II) complexes with inner sphere anionic ligands like NO3−, Br− and Cl−. Two of the complexes [Cu (L) NO3] NO3 (1) and [Cu (L) Br] Br (2) have been structurally characterized. The geometry of copper (II) in (1) is a distorted octahedral with NO3− anion acting as a ...

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